1310565-93-5Relevant articles and documents
Synthesis of C16-C27-fragments of bryostatins modified by 20,20-difluorination
Mears, Paul R.,Thomas, Eric J.
, p. 3975 - 3979 (2015)
Abstract 2-Hydroxytetrahydropyrans corresponding to the C16-C27 fragment of bryostatins which have been difluorinated at C20 (bryostatin numbering) have been synthesised. The fluorine substituents were introduced by difluoroallylation. An (E)-selective Wi
OPTICALLY ACTIVE FLUOROALKENE DERIVATIVE AND PRODUCTION METHOD THEREOF
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Paragraph 0031-0033, (2016/12/01)
PROBLEM TO BE SOLVED: To provide an optically active fluoroalkene derivative that is useful as a synthetic intermediate of medicines and agrochemicals, and a production method thereof. SOLUTION: An optically active fluoroalkene derivative and a method of
Copper mediated defluorinative allylic alkylation of difluorohomoallyl alcohol derivatives directed to an efficient synthetic method for (Z)-fluoroalkene dipeptide isosteres
Watanabe, Daisuke,Koura, Minoru,Saito, Akio,Yanai, Hikaru,Nakamura, Yuko,Okada, Midori,Sato, Azusa,Taguchi, Takeo
scheme or table, p. 327 - 338 (2011/06/27)
Difluoroallylation of optically pure O-silylated (S)-2-methyl-3- hydroxypropanal 10a with bromodifluoropropene mediated by indium provided the corresponding difluorohomoallyl alcohol 11a with low diastereoselectivity, but without a decrease in optical pur