131074-54-9

Upstream product

• 2043-61-0 cyclohexanecarbaldehyde 
• 762-72-1 allyl-trimethyl-silane 

Downstream Products

• 69036-26-6 1-cyclohexyl-3-buten-1-ol 
• 94340-22-4 (R)-1-cyclohexyl-3-buten-1-ol 
• 69036-26-6 (S)-1-cyclohexylbut-3-en-1-ol 

Relevant academic research and scientific papers

Cationic Cobalt Porphyrin-Catalyzed Allylation of Aldehydes with Allyltrimethylsilanes

Cationic cobalt porphyrin-catalyzed allylation of aldehydes with allyltrimethylsilanes is developed. The formation of the aldehyde-cobalt porphyrin complex, the key intermediate for the addition of allylsilanes, is confirmed by theoretical studies and syn

Mesoporous aluminosilicate-catalyzed allylation of carbonyl compounds and acetals

A mesoporous aluminosilicate (Al-MCM-41) was found to be an effective heterogeneous catalyst for the reaction of both carbonyl compounds and acetals with allylsilanes to afford the corresponding homoallyl silyl ethers and homoallyl alkyl ethers, respectively. Both the mesoporous structure and the presence of aluminum moiety were indispensable for the high catalytic activity of Al-MCM-41. Moreover, Al-MCM-41 could catalyze the reaction of acetals chemoselectively in the presence of the corresponding carbonyl compounds. The solid acid catalyst Al-MCM-41 could be recovered easily by filtration and could be reused three times without a significant loss of catalytic activity.

Mesoporous aluminosilicate-catalyzed allylation of aldehydes with allylsilanes

Mesoporous aluminosilicate (Al-MCM-41) was found to catalyze the allylation of both aromatic and aliphatic aldehydes with allylsilanes although amorphous silica-alumina or mesoporous silicates (MCM-41, SBA-15) could not catalyze the reaction under the sam

Montmorillonite K10 clay-catalyzed synthesis of homoallylic silyl ethers: an efficient and environmentally friendly Hosomi-Sakurai reaction

Aromatic aldehydes react with allyltrimethylsilane in the presence of activated Montmorillonite K10 clay to give homoallylic silyl ethers in good to excellent yields.

Monomeric metal aqua complexes in the interlayer space of montmorillonites as strong Lewis acid catalysts for heterogeneous carbon-carbon bond-forming reactions

Montmorillonite-enwrapped copper and scandium catalysts (Cu2-- and Sc3+-monts) were easily prepared by treating Na--mont with the aqueous solution of the copper nitrate and scandium triflate, respectively. The resulting Cu2+- and Sc3+-monts showed outstanding catalytic activities for a variety of carbon-carbon bond-forming reactions, such as the Michael reaction, the Sakurai-Hosomi allylation, and the Diels-Alder reaction, under solvent-free or aqueous conditions. The remarkable activity of the mont catalysts is attributable to the negatively charged silicate layers that are capable of stabilizing metal cations. Furthermore, these catalysts were reusable without any appreciable loss in activity and selectivity. The Cu2+-mont-catalyzed Michael reaction proceeds via a ternary complex in which both the 1,3-dicarbonyl compound and the enone are coordinated to a Lewis acid Cu2+ center.

Ytterbium trichloride-catalyzed allylation of aldehydes with allyltrimethylsilane

Ytterbium chloride (YbCl3) is found to be an effective catalyst for the allylation of both aromatic and aliphatic aldehydes using allyltrimethylsilane.

Super-acid Catalysed Addition of Allylsilanes to Carbonyl Compounds; Synthetic and Mechanistic Aspects

The addition of allyltrimethylsilane 8 to a variety of aldehydes and one ketone (cyclohexanone) was found to be induced by the super-acid TfOH2(1+)B(OTf)4(1-) (Tf = CF3SO2).In contrast to the analogous Lewis acid catalysed reaction, only catalytic amounts

Superacid Catalysis of the Addition of Allysilanes to Carbonyl Compounds

The superacid TfOH2+B(OTf)4- (Tf = CF3SO2) was found to catalyse the addition of trialkylallysilanes to aldehydes and a ketone (the Sakurai reaction) at levels of ca. 0.5 molpercent; the reactions were clean, highly-yielding, and reg