131079-28-2Relevant academic research and scientific papers
Synthesis and structure of a monomeric diarylstannylene
Grützmacher, Hansj?rg,Pritzkow, Hans,Edelmann, Frank T.
, p. 23 - 25 (2008/10/08)
The novel diarylstannylene bis[2,4,6-tris(trifluoromethyl)phenyl]stannylene 1 is synthesized conventionally from [2,4,6-(trifluoromethyl)phenyl]lithium and tin-(II) chloride. It is a monomer in the solid state, as shown by an X-ray analysis, and is stabilized by intramolecular fluorine-tin contacts, which NMR data indicate also exist in solution. Compound 1 (C18H4F18Sn) crystallizes in the monoclinic space group P21/a (Z = 4) with a = 11.915 (6) ?, b = 13.801 (7) ? c = 12.961 (7) ?, β = 93.56 (4)°, and V = 2172.2 ?3.
