1310800-15-7Relevant articles and documents
Design of chiral sulfoxide-olefins as a new class of sulfur-based olefin ligands for asymmetric catalysis
Qi, Wei-Yi,Zhu, Ting-Shun,Xu, Ming-Hua
supporting information; experimental part, p. 3410 - 3413 (2011/08/22)
The design and development of a novel class of chiral sulfur-olefin hybrid ligands with high synthetic feasibility are described. These new sulfoxide-olefin ligands showed excellent catalytic activities and enantioselectivities (up to 98% ee) in rhodium-catalyzed asymmetric 1,4-addition reactions of aryl boronic acids to α,β-unsaturated carbonyl compounds.