1310872-68-4Relevant academic research and scientific papers
Gold(I)-catalyzed bis-alkynylation reaction of aromatic aldehydes with alkynylsilanes
Rubial, Belen,Ballesteros, Alfredo,Gonzalez, Jose M.
supporting information, p. 3337 - 3343 (2013/12/04)
The first successful gold(I)-catalyzed reaction of aryl aldehydes with trimethyl(arylethynyl)silanes to furnish bis-alkynylated derivatives is reported. Key C-C bond-forming events involved in the catalytic cycle are analyzed. Copyright
Aryl aldehydes as traceless dielectrophiles in bifunctional titanocene-catalyzed propargylic C-X activations
Campos, Catherine A.,Gianino, Joseph B.,Pinkerton, David M.,Ashfeld, Brandon L.
supporting information; experimental part, p. 5680 - 5683 (2011/12/04)
The titanocene-catalyzed construction of all-carbon substituted tertiary centers directly from aromatic aldehydes is described. The starting aldehyde behaves as a traceless functionality in the formation of multiple carbon-carbon bonds through consecutive
Atom-economical chemoselective synthesis of 1,4-diynes and polysubstituted furans/pyrroles from propargyl alcohols and terminal alkynes
Wang, Tao,Chen, Xin-Liang,Chen, Li,Zhan, Zhuang-Ping
supporting information; experimental part, p. 3324 - 3327 (2011/09/12)
Under different conditions, the reaction of propargyl alcohols and terminal alkynes leads to the selective formation of 1,4-diynes and polysubstituted furans/pyrroles. Water is the only byproduct in the selective synthesis of 1,4-diynes and pyrroles, and
