1311144-95-2Relevant academic research and scientific papers
Alkoxyamine-cyanoborane adducts: Efficient cyanoborane transfer agents
Marquez, Jose M.,Martinez-Castro, Elisa,Gabrielli, Serena,Lopez, Oscar,Maya, Ines,Angulo, Manuel,Alvarez, Eleuterio,Fernandez-Bolanos, Jose G.
supporting information; experimental part, p. 5617 - 5619 (2011/06/26)
We report the synthesis of the hitherto unknown zwitterionic alkoxyamino cyanoboranes by reduction of O-alkyloximes with sodium cyanoborohydride; unprecedented cyanoboronated N-alkoxyformamidines were also isolated as by-products. Boronated alkoxyamines were found to be efficient cyanoborane transfer agents towards more basic amines, including aminosugars; they were also successfully transformed into neoglycoconjugates by the neoglycorandomization reaction with reducing sugars.
