1311174-85-2

Upstream product

• 1311174-98-7 (1S,3aR,6S,7aS)-4-{2-[(1S,3S)-3-(tert-butyldiphenylsilyloxy)-1-(methoxymethoxy)-2-methylenecyclohexyl]ethyl}-6-hydroxy-1-(methoxymethoxy)-7a-methyl-2,3,3a,6,7,7a-hexahydro-1H-inden-5-yl trifluoromethanesulfonate 
• 108-24-7 acetic anhydride 
• 1311174-84-1 (1S,3aR,7aS)-4-{2-[(1S,3S)-3-(tert-butyldiphenylsilyloxy)-1-(methoxymethoxy)-2-methylenecyclohexyl]ethyl}-1-(methoxymethoxy)-7a-methyl-6-oxo-2,3,3a,6,7,7a-hexahydro-1H-inden-5-yl trifluoromethanesulfonate 
• 1311174-83-0 (1S,3aS,4R,7aS)-4-{2-[(1S,3S)-3-(tert-butyldiphenylsilyloxy)-1-(methoxymethoxy)-2-methylenecyclohexyl]ethyl}-6-hydroxy-1-(methoxymethoxy)-7a-methylhexahydro-1H-inden-5(6H)-one 
• 1311174-82-9 (1S,3aS,4R,7aS)-4-{2-[(1S,3S)-3-(tert-butyldiphenylsilyloxy)-1-(methoxymethoxy)-2-methylenecyclohexyl]ethyl}-1-(methoxymethoxy)-7a-methylhexahydro-1H-inden-5(6H)-one 
• 1311174-81-8 (1S,3aS,4R,7aS)-4-{2-[(1S,3S)-3-hydroxy-1-(methoxymethoxy)-2-methylenecyclohexyl]ethyl}-1-(methoxymethoxy)-7a-methylhexahydro-1H-inden-5(6H)-one 
• 1311174-80-7 (1S,3aS,4R,7aS)-4-{2-[(1S,2S,6S)-1-(iodomethyl)-2-(methoxymethoxy)-7-oxabicyclo[4.1.0]heptan-2-yl]ethyl}-1-(methoxymethoxy)-7a-methylhexahydro-1H-inden-5(6H)-one 
• 1311174-79-4 (1S,3aS,4S,7aS)-4-{2-[(1S,2S,6S)-1-(hydroxymethyl)-2-(methoxymethoxy)-7-oxabicyclo[4.1.0]heptan-2-yl]ethyl}-1-(methoxymethoxy)-7a-methylhexahydro-1H-inden-5(6H)-one 
• 1311174-78-3 C₃₅H₆₆O₇Si₂ 

Downstream Products

• 1311174-92-1 tert-butyl {(3S,3aS,7S,10aS,12aS,12bR)-3-(methoxymethoxy)-3a-methyl-1,2,3,3a,4,7,8,9,10,11,12,12b-dodecahydro-10a,12a-epoxybenzo[4,5]cyclohepta[1,2-e]inden-7-yl}oxydiphenylsilane 
• 1311174-88-5 (3S,3aS,5S,6aR,7S,10aS,12bS)-7-[(tert-butyldiphenylsilyl)oxy]-3,10a-bis(methoxymethoxy)-3a-methyl-1,2,3,3a,4,5,6a,7,8,9,10,10a,11,12b-tetradecahydrobenzo[4,5]cyclohepta[1,2-e]inden-5-yl acetate 
• 1311174-87-4 (3S,3aS,5S,7S,10aS,12bS)-7-[(tert-butyldiphenylsilyl)oxy]-3,10a-bis(methoxymethoxy)-3a-methyl-1,2,3,3a,4,5,7,8,9,10,10a,11,12,12b-tetradecahydrobenzo[4,5]cyclohepta[1,2-e]inden-5-yl acetate 
• 1311175-00-4 (3S,3aS,5S,7aR)-7-{2-[(1S,3S)-3-(tert-butyldiphenylsilyloxy)-1-hydroxy-2-methylenecyclohexyl]ethyl}-3-(methoxymethoxy)-3a-methyl-6-(trifluoromethylsulfonyloxy)-2,3,3a,4,5,7a-hexahydro-1H-inden-5-yl acetate 
• 1311174-86-3 (3S,3aS,5S,7aR)-7-{2-[(1S,3S)-3-(tert-butyldiphenylsilyloxy)-2-methylene-1-(trimethylsilyloxy)cyclohexyl]ethyl}-3-(methoxymethoxy)-3a-methyl-6-(trifluoromethylsulfonyloxy)-2,3,3a,4,5,7a-hexahydro-1H-inden-5-yl acetate 
• 1311175-02-6 (3S,3aS,5S,7S,10aS,12bS)-7-(tert-butyldiphenylsilyloxy)-3-(methoxymethoxy)-3a-methyl-10a-(trimethylsilyloxy)-1,2,3,3a,4,5,7,8,9,10,10a,11,12,12b-tetradecahydrobenzo[4,5]cyclohepta[1,2-e]inden-5-yl acetate 
• 1311174-89-6 (3S,3aS,5S,7S,10aS,12bS)-7-(tert-butyldiphenylsilyloxy)-10a-hydroxy-3-(methoxymethoxy)-3a-methyl-1,2,3,3a,4,5,7,8,9,10,10a,11,12,12b-tetradecahydrobenzo[4,5]cyclohepta[1,2-e]inden-5-yl acetate 
• 1311175-04-8 (3S,3aS,5S,7S,10aS,12bS)-7-(tert-butyldiphenylsilyloxy)-3-(methoxymethoxy)-3a-methyl-1,2,3,3a,4,5,7,8,9,10,10a,11,12,12b-tetradecahydrobenzo[4,5]cyclohepta[1,2-e]indene-5,10a-diol 
• 1311174-90-9 (3S,3aS,7S,10aS,12bS)-7-(tert-butyldiphenylsilyloxy)-10a-hydroxy-3-(methoxymethoxy)-3a-methyl-1,2,3,3a,4,8,9,10,10a,11,12,12b-dodecahydrobenzo[4,5]cyclohepta[1,2-e]inden-5(7H)-one 
• 1311174-91-0 (3S,3aS,5aS,7S,10aS,12aS,12bR)-7-(tert-butyldiphenylsilyloxy)-3-(methoxymethoxy)-3a-methyl-1,2,3,3a,4,7,8,9,10,11,12,12b-dodecahydro-10a,12a-epoxybenzo[4,5]cyclohepta[1,2-e]inden-5(5aH)-one 
• 1311175-05-9 (3S,3aS,5R,5aR,7S,10aS,12aS,12bR)-7-(tert-butyldiphenylsilyloxy)-3-(methoxymethoxy)-3a-methyl-1,2,3,3a,4,5,5a,7,8,9,10,11,12,12b-tetradecahydro-10a,12a-epoxybenzo[4,5]cyclohepta-[1,2-e]inden-5-ol 

Relevant academic research and scientific papers

Stereoselective synthesis of core structure of cortistatin A

A stereoselective synthesis of the core structure of cortistatin A (1), a novel antiangiogenic steroidal alkaloid from Indonesian marine sponge, is described. An 8-oxabicyclo[3.2.1]octene system, a characteristic B-ring structure of 1, was elaborated by a 7-endo selective intramolecular Heck cyclization and a subsequent acid-mediated oxy-Michael reaction.