1311202-69-3Relevant academic research and scientific papers
Switch in stereoselectivity caused by the isocyanide structure in the rhodium-catalyzed silylimination of alkynes
Fukumoto, Yoshiya,Hagihara, Motoyuki,Kinashi, Fuyuko,Chatani, Naoto
supporting information; experimental part, p. 10014 - 10017 (2011/08/22)
The reaction of terminal alkynes with hydrosilanes and tert-alkyl isocyanides in the presence of Rh4(CO)12 gives (Z)-β-silyl-α,β-unsaturated imines in good yields. On the other hand, the use of aryl isocyanides in place of tert-alkyl isocyanides leads to the formation of E isomers.
