13114-20-0

Basic information

• Product Name: N-[(2E)-3,3-dimethylbutan-2-ylidene]aniline
• CAS NO: 13114-20-0
• Molecular Formula: C₁₂H₁₇N
• Molecular Weight: 175.2701
• Mol File: 13114-20-0.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 229.9°C at 760 mmHg
• Flash Point: 84.4°C
• Density: 0.86g/cm³
• Vapor Pressure: 0.103mmHg at 25°C
• Refractive Index: 1.482
• CAS DataBase Reference: N-[(2E)-3,3-dimethylbutan-2-ylidene]aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-[(2E)-3,3-dimethylbutan-2-ylidene]aniline(13114-20-0)
• EPA Substance Registry System: N-[(2E)-3,3-dimethylbutan-2-ylidene]aniline(13114-20-0)

Safety Data

• Hazardous Substances Data: 13114-20-0(Hazardous Substances Data)

Upstream product

• 75-97-8 3,3-dimethyl-butan-2-one 
• 62-53-3 aniline 
• 917-92-0 3,3-Dimethylbut-1-yne 
• 203123-36-8 2,3,3-Trimethyl-2-phenylamino-butyronitrile 
• 917-54-4 methyllithium 
• 50993-08-3 N-phenyl-2,2-dimethylpropanimidoyl chloride 
• 1197040-29-1 phenyl isocyanate 
• 594-19-4 tert.-butyl lithium 
• 74-88-4 methyl iodide 

Downstream Products

• 175522-96-0 C₁₂H₁₉N 
• 81023-55-4 N-(4,4-Dimethyl-3-phenylimino-1-pentenyl)benzolamin 
• 75251-18-2 N-(2,2-Dimethyl-1-methylenpropyl)benzolamin 
• 81099-14-1 N-(4,4-Dimethyl-3-phenylimino-1-pentenyl)-N,N'-diphenylformamidin 
• 63386-21-0 N-<1-(1,1-Dimethylethyl)-4,4-dimethyl-3-phenylimino-1-pentenyl>benzolamin 
• 81023-64-5 N,N-Diisopropyl-N'-phenylpivalamidin 
• 13988-67-5 benzoylpivaloylmethane 
• 75251-05-7 N-(2,2-dimethyl-1-methylenepropyl)-N-lithiobenzeneamine 

Relevant articles and documents

Synthesis of 3-acetyl-4-hydroxy-1-phenylpyridin-2(1H)-one derivatives

The cyclization of aryl ketone anilides 3 with diethyl malonate to affords 4-hydroxy-6-phenyl-6H-pyrano [3,2-c]-pyridin-2,5-diones 4 in good yields. 3-Acetyl-4-hydroxy-1-phenylpyridin-2(1H)-ones 5 are obtained by ring-opening reaction of 4-hydroxy-6-pheny

Synthesis of bifunctional Au-Sn organic-inorganic catalysts for acid-free hydroamination reactions

Gold(III) complexes heterogenized on the surface of a Sn-containing MCM-41 are efficient recyclable catalysts for hydroamination reactions, without requiring any acid promoters. The Royal Society of Chemistry.

The Crystallographic Characterization of an Unusual Chemical Reversal of Photoisomerization

Imines formed from pinacolone and primary amines could be acylated by acid chlorides or anhydrides to products hydrolysable to 1,3-diones.Benzoyl chloride with pinacolone benzylimine gave 3-(N-benzoyl-N-benzylamino)-4,4-dimethyl-1-phenylpent-2-en-1-one, both geometrical isomers of which were prepared.The yellow Z isomer was converted into the colourless E isomer on exposure to daylight and this change was reversed by brief treatment of the E isomer with aqueous ethanolic alkali.The Z and E isomers have been characterized crystallographically.The E isomer is monoclinic, C2/c, a 10.241(4), b 17.199(6), c 25.495(9) Angstroem, β 100.45(3) deg, Z = 8; R was 0.052 for 1947 'observed reflections.The Z-isomer is orthorhombic, P212121, a 18.24(1), b 15.60(1), c 7.871(4) Angstroem, Z = 4; R was 0.61 for 902 'observed' reflections.