1311408-35-1Relevant articles and documents
Ligand-free nickel-catalyzed semihydrogenation of alkynes with sodium borohydride: A highly efficient and selective process for: Cis -alkenes under ambient conditions
Wen, Xin,Shi, Xiaozhen,Qiao, Xianliang,Wu, Zhilei,Bai, Guoyi
, p. 5372 - 5375 (2017)
We report a low-cost and efficient catalytic system, involving in situ generated ligand-free Ni NPs, methanol and sodium borohydride, for the semihydrogenation of alkynes under ambient conditions. This catalytic system exhibits remarkably high activity, satisfactory cis-selectivity for internal alkynes, good stability and general applicability.