1312080-32-2

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 139026-03-2 (E)-4-Methyl-4,6-heptadienal 
• 104846-46-0 (4E)-5-iodo-4-methylpent-4-en-1-ol 
• 118419-29-7 6-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)hex-2-yn-1-ol 
• 113375-54-5 (4E)-4-Methylhepta-4,6-dien-1-ol 
• 91266-03-4 tert-butyl-pent-4-ynyloxy-diphenyl-silane 
• 1312080-45-7 (E)-5-methyl-1,1-diphenylocta-5,7-dien-2-ol 
• 1312080-31-1 (2Z)-1-((tert-butyloxycarbonyl)oxy)-6-(tert-butyldiphenylsiloxy)-2-((E)-7-methoxy-4-methyl-8,8-diphenyloct-3-enyl)hex-2-ene 
• 1312080-30-0 tert-butyl (2E)-6-((tert-butyldiphenylsilyl)oxy)-2-iodohex-2-en-1-yl carbonate 
• 1312080-46-8 (E)-6-(tert-butyldiphenylsiloxy)-2-iodohex-2-en-1-ol 
• 1312080-29-7 (E)-7-methoxy-4-methyl-8,8-diphenylocta-1,3-diene 

Downstream Products

• 1312080-33-3 (5R,6R)-6-(3-((tert-butyldiphenylsilyl)oxy)propyl)-8-((2S)-5-methoxy-2-methyloxolan-2-yl)-1,3,7-trioxaspiro[4.5]decan-2-one 
• 1312080-51-5 (5R,6R)-6-(3-((tert-butyldiphenylsilyl)oxy)propyl)-8-((2S)-2-methyl-5-oxooxolan-2-yl)-1,3,7-trioxaspiro[4.5]decan-2-one 
• 1312080-52-6 (S)-5-((2R,5R,6R)-6-(3-(tert-butyldiphenylsilyloxy)propyl)-5-hydroxy-5-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)-5-methyldihydrofuran-2(3H)-one 
• 1312080-53-7 (2R,6R)-2-(3-(tert-butyldiphenylsilyloxy)propyl)-6-((S)-2-methyl-5-oxotetrahydrofuran-2-yl)dihydro-2H-pyran-3(4H)-one 
• 1312080-54-8 (S)-5-((2R,5S,6R)-6-(3-(tert-butyldiphenylsilyloxy)propyl)-5-hydroxytetrahydro-2H-pyran-2-yl)-5-methyldihydrofuran-2(3H)-one 
• 1312080-55-9 (S)-((2R,3S,6R)-2-(3-(tert-butyldiphenylsilyloxy)propyl)-6-((S)-2-methyl-5-oxotetrahydrofuran-2-yl)tetrahydro-2H-pyran-3-yl)-3,3,3-trifluoro-2-methoxy-2-phenylpropanoate 
• 1312080-56-0 (R)-((2R,3S,6R)-2-(3-(tert-butyldiphenylsilyloxy)propyl)-6-((S)-2-methyl-5-oxotetrahydrofuran-2-yl)tetrahydro-2H-pyran-3-yl)-3,3,3-trifluoro-2-methoxy-2-phenylpropanoate 

Relevant academic research and scientific papers

Total synthesis of the protein phosphatase 2A inhibitor lactodehydrothyrsiferol

Cascading epoxides: The squalene-derived polyether lactodehydrothyrsiferol (1) has been prepared through a convergent sequence that features an epoxide-opening cascade to construct the tetrahydrofuran and tetrahydropyran subunits. Additional features include a stereodivergent diene diepoxidation, a monodeoxygenation of a triol, and complex fragment couplings through Suzuki and Nozaki-Hiyama-Kishi reactions. Copyright