1312290-48-4Relevant academic research and scientific papers
Such pyridine skeleton of a chiral shan lin ligand CF - Phos and its preparation method and application (by machine translation)
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, (2019/05/02)
The invention discloses a pyridine skeleton of chiral shan lin ligand CF - Phos and its preparation method and application, the [...] ligand is compound 1 or compound 1 of the enantiomer, racemate and diastereoisomer; the ligand to the preparation method of the compound is and As the raw material, the condensation reaction, the substitution reaction, hydrolysis reaction, addition reaction for preparing the states shan lin ligand; or in order to compound and As the raw material, a condensation reaction, and or The addition reaction for preparing the states shan lin ligand. The present invention through the use of two configurations of the compound And different types of metal reagent addition reaction, can be obtained by states chiral shan lin ligand i.e. compound 1 (S, Rs ), 1 (R, Rs ), 1 (S, Ss ) And 1 (R, Ss ) Of four full-configuration of optically pure. The invention also discloses the ligands copper catalytic unsaturated carboxylic acid in the application of the asymmetric lactonization reaction, has wide application value. (by machine translation)
Reversible anion-templated self-assembly of [2+2] and [3+3] metallomacrocycles containing a new dicopper(i) motif
Dry, Emily F. V.,Clegg, Jack K.,Breiner, Boris,Whitaker, Daniel E.,Stefak, Roman,Nitschke, Jonathan R.
, p. 6021 - 6023 (2011/08/02)
A new dicopper(i) complex is reported that can be incorporated into extended architectures through multitopic carboxylate linkers; reversible carboxylate templation under pH control led to the formation of [2+2] and [3+3] metallomacrocycles.
