131231-61-3Relevant articles and documents
Neue Wege zu Polysilanen
Hengge, Edwin,Kalchauer, Wilfried
, p. 793 - 802 (1990)
Disilane dervatives undergo disproportionation reactions to polysilanes.Investigated were 1,2-dimethyldisilane and 1,2-dimethyltetrachlorodisilane with catalysts like NH4Cl, AgCN, and Na-cyanamide.In case of 1,2-dimethylsilane, with more than catalytic amounts of NH4Cl, a nitrogen containing polysilane is formed.Two new compounds MeSiH(NCO)2 and Me2Si2(NCO)4 were synthesized and characterized.The last one leads to a polymer at heating.Additionally an electrochemical formation of polydimethylsilane is described.