1312319-97-3

Basic information

• Product Name: C₁₄H₁₆O
• Synonyms: C₁₄H₁₆O
• CAS NO: 1312319-97-3
• Molecular Weight: 200.28
• Mol File: 1312319-97-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₆O(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₆O(1312319-97-3)
• EPA Substance Registry System: C₁₄H₁₆O(1312319-97-3)

Safety Data

• Hazardous Substances Data: 1312319-97-3(Hazardous Substances Data)

Upstream product

• 119405-97-9 4-phenyl-1,1-dibromo-1-butene 
• 1312319-96-2 C₁₄H₁₆O 
• 1312320-06-1 C₂₀H₃₂OSi 

Relevant articles and documents

Rh(I)-catalyzed formal [6 + 2] cycloaddition of 4-allenals with alkynes or alkenes in a tether

Rh(I)-catalyzed formal [6 + 2] cycloaddition of allenal 6 having an alkyne or alkene in a tether proceeded smoothly, giving 5-8- and 6-8-fused bicyclic ketone derivatives 7 in good to excellent yields. It was also found that cyclization of enantiomerically enriched (S)-6a (94% ee) gave cyclic ketone derivative (S)-7a in high yield with reasonable chirality transfer (86% ee). This result indicates that this cyclization proceeds through stereoselective formation of rhodacycle H′ followed by insertion of a multiple bond.