131232-90-1

Basic information

• Product Name: 2,6-Dimethyltricyclo<5.2.1.0^2,6>decan-3-one Tosylhydrazone
• Synonyms: 2,6-Dimethyltricyclo<5.2.1.0^2,6>decan-3-one Tosylhydrazone
• CAS NO: 131232-90-1
• Molecular Weight: 346.494
• Mol File: 131232-90-1.mol

Chemical Properties

• CAS DataBase Reference: 2,6-Dimethyltricyclo<5.2.1.0^2,6>decan-3-one Tosylhydrazone(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-Dimethyltricyclo<5.2.1.0^2,6>decan-3-one Tosylhydrazone(131232-90-1)
• EPA Substance Registry System: 2,6-Dimethyltricyclo<5.2.1.0^2,6>decan-3-one Tosylhydrazone(131232-90-1)

Safety Data

• Hazardous Substances Data: 131232-90-1(Hazardous Substances Data)

Upstream product

• 66701-34-6 (-)-(1R,2S,6R,7S)-2,6-dimethyltricyclo[5.2.1.0^2,6]decan-3-one 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 131232-89-8 (-)-(1R,2S,6S,7S)-2,6-dimethyltricyclo[5.2.1.0^2,6]dec-4-en-3-one 
• 131232-88-7 (1R,2S,6R,7S)-6-Methyltricyclo<5.2.1.0^2,6>decan-3-one 
• 67518-96-1 3,3-Dimethyl-bicyclo<2.2.1>hept-2-exo-yl-carbonic acid 
• 67596-91-2 (+)-Isocamphenilansaeurechlorid 
• 131232-77-4 6-Methyltricyclo<5.2.1.0^2,6>decen-3-one 

Relevant articles and documents

Site-Selective Rhodium(II) Acetate Mediated Intramolecular Metal-Carbene Insertions into C-H Bonds of Bicycloheptanes: Efficient Syntheses of (+)-Albene and (-)-β-Santalene

Treatment of α-diazo ketones 1a-d and 2a-d with catalytic amounts of rhodium(II) acetate led to selective carbene insertions into C-H bonds resulting in cyclopentane-annulated products in high yields.The highly selective insertion realized into the exo-methyl C-H bond of 1a has been utilized in the syntheses of (+)-albene (8) and (-)-β-santalene (11).