1312341-54-0

Basic information

• Product Name: (R)-4-benzyl-3-((2R,3S)-2-chloro-3-hydroxy-3-((1R,2S)-2-isopropylcyclopropyl)propanoyl)-5,5-dimethyloxazolidin-2-one
• Synonyms: (R)-4-benzyl-3-((2R,3S)-2-chloro-3-hydroxy-3-((1R,2S)-2-isopropylcyclopropyl)propanoyl)-5,5-dimethyloxazolidin-2-one
• CAS NO: 1312341-54-0
• Molecular Weight: 393.911
• Mol File: 1312341-54-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-4-benzyl-3-((2R,3S)-2-chloro-3-hydroxy-3-((1R,2S)-2-isopropylcyclopropyl)propanoyl)-5,5-dimethyloxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-4-benzyl-3-((2R,3S)-2-chloro-3-hydroxy-3-((1R,2S)-2-isopropylcyclopropyl)propanoyl)-5,5-dimethyloxazolidin-2-one(1312341-54-0)
• EPA Substance Registry System: (R)-4-benzyl-3-((2R,3S)-2-chloro-3-hydroxy-3-((1R,2S)-2-isopropylcyclopropyl)propanoyl)-5,5-dimethyloxazolidin-2-one(1312341-54-0)

Safety Data

• Hazardous Substances Data: 1312341-54-0(Hazardous Substances Data)

Upstream product

• 870196-41-1 (R)-4-benzyl-3-(2-chloroacetyl)-5,5-dimethyl-2-one 
• 1312341-53-9 (R)-4-benzyl-3-((2R,3S,E)-2-chloro-3-hydroxy-6-methylhept-4-enoyl)-5,5-dimethyloxazolidin-2-one 
• 204851-73-0 (R)-(+)-4-benzyl-5,5-dimethyl-2-oxazolidinone 

Downstream Products

• 1312341-55-1 (R)-4-benzyl-3-((R)-3-hydroxy-3-((1R,2S)-2-isopropylcyclopropyl)propanoyl)-5,5-dimethyloxazolidin-2-one 
• 147659-07-2 (+)-prelactone B 

Relevant articles and documents

Asymmetric synthesis of chiral δ-lactones containing multiple contiguous stereocenters

A versatile methodology for the asymmetric synthesis of chiral δ-lactones containing multiple contiguous stereocenters has been developed that relies on a series of Evans' aldol, hydroxyl-directed cyclopropanation, methanolysis, and Hg(II) mediated cyclopropane ring-opening reactions for stereocontrol.