1312366-29-2Relevant academic research and scientific papers
Ruthenium-catalyzed regio- and enantioselective allylic substitution with water: Direct synthesis of chiral allylic alcohols
Kanbayashi, Naoya,Onitsuka, Kiyotaka
supporting information; experimental part, p. 5197 - 5199 (2011/06/26)
Less is more: A new route to access chiral allylic alcohols through the regio- and enantioselective substitution of monosubstituted allylic chlorides with water has been developed. The reaction is catalyzed effectively by planar-chiral cyclopentadienyl ruthenium complexes (see scheme). Copyright
