1312447-94-1

Basic information

• Product Name: N-Ts-2-(3'-methoxyphenyl)aniline
• Synonyms: N-Ts-2-(3'-methoxyphenyl)aniline
• CAS NO: 1312447-94-1
• Molecular Weight: 353.442
• Mol File: 1312447-94-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: N-Ts-2-(3'-methoxyphenyl)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-Ts-2-(3'-methoxyphenyl)aniline(1312447-94-1)
• EPA Substance Registry System: N-Ts-2-(3'-methoxyphenyl)aniline(1312447-94-1)

Safety Data

• Hazardous Substances Data: 1312447-94-1(Hazardous Substances Data)

Upstream product

• 615-43-0 2-iodophenylamine 
• 2398-37-0 3-methoxyphenyl bromide 
• 796061-07-9 4-methyl-N-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)benzenesulfonamide 
• 615-36-1 2-bromoaniline 
• 98-59-9 p-toluenesulfonyl chloride 
• 38089-02-0 3'-methoxy-[1,1'-biphenyl]-2-amine 
• 10365-98-7 3-methoxyphenylboronic acid 

Downstream Products

• 1174643-97-0 2-methoxy-9-p-toluenesulfonylcarbazole 
• 1426813-05-9 9-methoxy-5-tosylphenanthridin-6(5H)-one 
• 1312447-79-2 3-methoxy-9-tosyl-9H-carbazole 

Relevant articles and documents

Catalytic Synthesis of Dibenzazepines and Dibenzazocines by 7-Exo- and 8-Endo-Dig-Selective Cycloisomerization

The 7-exo- and 8-endo-dig-selective gold-catalyzed cycloisomerizations of 2-propargylamino biphenyl derivatives were developed. The reaction of terminal alkynes gave dibenzo[b,d]azepines by 7-exo-dig cycloisomerization. In contrast, when internal alkynes were subjected to the reaction, 8-endo-dig cycloisomerization proceeded to provide dibenzo[b,d]azocines. The nucleophilicity at the reaction site and the electron-withdrawing effect of a tosyl group were important for the present selective transformation. This protocol could be used for ynamide substrates and a silver-catalyzed reaction gave 7-exo-dig products selectively.

Palladium-catalyzed oxidative insertion of carbon monoxide to N -sulfonyl-2-aminobiaryls through C-H bond activation: Access to bioactive phenanthridinone derivatives in one pot

Palladium-catalyzed oxidative carbonylation of N-sulfonyl-2-aminobiaryls through C-H bond activation and C-C, C-N bond formation under TFA-free and milder conditions has been developed. The reaction tolerates a variety of substrates and provides biologically important phenanthridinone derivatives in yields up to 94%.