1312680-97-9Relevant academic research and scientific papers
Catalytic asymmetric C-H insertions of rhodium(II) azavinyl carbenes
Chuprakov, Stepan,Malik, Jamal A.,Zibinsky, Mikhail,Fokin, Valery V.
supporting information; experimental part, p. 10352 - 10355 (2011/08/05)
A highly efficient enantioselective C-H insertion of azavinyl carbenes into unactivated alkanes has been developed. These transition metal carbenes are directly generated from readily available and stable 1-sulfonyl-1,2,3-triazoles in the presence of chiral Rh(II) carboxylates and are used for C-H functionalization of alkanes to access a variety of β-chiral sulfonamides.
