1312767-99-9

Upstream product

• 1312768-01-6 6-[3'-[(tert-butyldimethylsilyl)oxy]-4'-methylpent-4'-en-1-yl]-3-methoxycyclohex-2-en-1-one 
• 1312768-11-8 (3RS)-5-[(4-methoxyphenyl)methoxy]-2-methylpent-1-en-3-ol 
• 1312768-12-9 (3RS)-tert-butyl{5-[(4-methoxyphenyl)methoxy]-2-methylpent-1-en-3-yloxy}dimethylsilane 

Downstream Products

• 869898-86-2 (±)-platencin 
• 1312768-13-0 2-(2'-bromoprop-2'-en-1'-yl)-6-[3''-hydroxy-4''-methylpent-4''-en-1''-yl]-3-methoxycyclohex-2-en-1-one 
• 1354552-76-3 C₂₀H₂₈O₃ 
• 1354552-57-0 6-(3-hydroxy-4-methylpentyl)-3-methoxycyclohex-2-enone 
• 1354552-73-0 C₂₀H₂₆O₃ 
• 1354552-72-9 C₁₄H₂₂O₃ 
• 1412281-19-6 (S)-6-((R)-3-hydroxy-4-methylpent-4-enyl)-3-methoxy-6-methylcyclohex-2-enone 
• 1412280-87-5 (R)-5-((R)-4-methoxy-1-methyl-2-oxocyclohex-3-enyl)-2-methylpent-1-en-3-yl acetate 
• 1412280-90-0 (R)-3-methoxy-6-methyl-6-(4-methylpent-4-enyl)cyclohex-2-enone 
• 1412280-94-4 (R)-4-methyl-4-(4-methylpent-4-enyl)-3-vinylcyclohex-2-enone 

Relevant academic research and scientific papers

Stereoselective α-quaternization of 3-methoxycycloalk-2-enones via 1,4-diastereoinduction of alkoxy dienolates

The alkylation of dienolates generated from 3-methoxycycloalk-2-enones having a 3′-hydroxyl alkenyl chain provides the corresponding quaternized cycloalkenones in a highly diastereoselective manner. The high degree of stereocontrol in the α-quaternization possibly implies intervention of a rigid chelating transition state that allows an efficient 1,4-asymmetric induction to take place.

Total synthesis of (±)-platencin

A novel route to (±)-platencin is reported, in which the highly stereoselective alkylative quaternization of a cyclohexenone scaffold via 1,4-diastereoinduction and two radical carbon-carbon bond-forming reactions that involve titanium(III)-mediated cycli