1312776-16-1

Basic information

• Product Name: 5-bromo-5-cyclohexylidene-2-methylenepentanenitrile
• Synonyms: 5-bromo-5-cyclohexylidene-2-methylenepentanenitrile
• CAS NO: 1312776-16-1
• Molecular Weight: 254.17
• Mol File: 1312776-16-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-bromo-5-cyclohexylidene-2-methylenepentanenitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 5-bromo-5-cyclohexylidene-2-methylenepentanenitrile(1312776-16-1)
• EPA Substance Registry System: 5-bromo-5-cyclohexylidene-2-methylenepentanenitrile(1312776-16-1)

Safety Data

• Hazardous Substances Data: 1312776-16-1(Hazardous Substances Data)

Upstream product

• 1192-37-6 methylenecyclohexane 
• 56424-67-0 1,1-Dibromospiro[2,5]octan 
• 5664-20-0 vinylidenecyclohexane 
• 17200-53-2 α-(bromomethyl)acrylonitrile 

Relevant articles and documents

Regioselective radical bromoallylation of allenes leading to 2-bromo-substituted 1,5-dienes

The regioselective radical bromoallylation of allenes proceeded efficiently in the presence of AIBN as a radical initiator to give 2-bromo-substituted 1,5-dienes in excellent yields. The addition of a bromine radical took place regioselectively onto the central carbon of allenes generating a stable allyl radical, which underwent addition/β-fragmentation reactions with allylbromides. The products could be further functionalized by Pd-catalyzed coupling reactions.