1312926-11-6

Basic information

• Product Name: tert-butyl benzyloxy(2-nitro-1-phenylethyl)carbamate
• Synonyms: tert-butyl benzyloxy(2-nitro-1-phenylethyl)carbamate
• CAS NO: 1312926-11-6
• Molecular Weight: 372.421
• Mol File: 1312926-11-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: tert-butyl benzyloxy(2-nitro-1-phenylethyl)carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl benzyloxy(2-nitro-1-phenylethyl)carbamate(1312926-11-6)
• EPA Substance Registry System: tert-butyl benzyloxy(2-nitro-1-phenylethyl)carbamate(1312926-11-6)

Safety Data

• Hazardous Substances Data: 1312926-11-6(Hazardous Substances Data)

Upstream product

• 102-96-5 (2-nitroethenyl)benzene 
• 79722-21-7 tert-butyl N-(benzyloxy)carbamate 
• 5153-67-3 nitrostyrene 

Downstream Products

• 137102-65-9 (R)-(2-amino-1-phenyl-ethyl)-carbamic acid tert-butyl ester 

Relevant articles and documents

Enantioselective amination of nitroolefins under base-free and water-rich conditions using chiral bifunctional phase-transfer catalysts

The direct enantioselective amination of nitroolefins has been performed with l-tert-leucine-derived squaramide-scaffold bifunctional phase-transfer catalysts under base-free and water-rich conditions with low catalyst loading (0.5-1 mol%) to provide 2-am

Asymmetric neutral amination of nitroolefins catalyzed by chiral bifunctional ammonium salts in water-rich biphasic solvent

It′s just a phase: Environmentally benign title reaction was achieved under neutral phase-transfer conditions in the presence of 0.05 mol% of a chiral bifunctional ammonium bromide. The importance of bifunctional design of the chiral phase-transfer catalysts (PTC) was clearly shown in the transition-state model of the reaction based on the single-crystal X-ray structure. Bn=benzyl, Boc=tert-butoxycarbonyl.