1313022-74-0Relevant articles and documents
Enantioselective allylic etherification: Selective coupling of two unactivated alcohols
Roggen, Markus,Carreira, Erick M.
supporting information; experimental part, p. 5568 - 5571 (2011/08/05)
An Ir(P,alkene) complex catalyzes the enantioselective allylic etherification of unactivated secondary allylic alcohols. Useful levels of enantioselectivity and yield were achieved with this operationally easy and robust protocol. Initial kinetic studies indicate a significant rate difference for the substrate enantiomers, allowing for a resolution process. cod=1,5-cyclooctadiene Copyright
