1313227-89-2Relevant academic research and scientific papers
In Situ Generated Magnesium Cyanide as an Efficient Reagent for Nucleophilic Cyanation of Nitrosoalkenes and Parent Nitronates
Ushakov, Pavel Yu.,Tabolin, Andrey A.,Ioffe, Sema L.,Sukhorukov, Alexey Yu.
, p. 1888 - 1892 (2019)
In situ generated magnesium cyanide [NaCN/Mg(ClO4)2] is suggested as a convenient, readily available, non-volatile and organic-soluble reagent for hydrocyanation reactions. It was successfully used for nucleophilic cyanation of nitrosoalkenes, nitronates, as well as other typical π-electrophiles, such as imines, α,β-unsaturated ketones, alkylidenemalonates and azoalkenes.
A general metal-assisted synthesis of α-halo oxime ethers from nitronates and nitro compounds
Sukhorukov, Alexey Yu.,Kapatsyna, Maria A.,Yi, Tammy Lim Ting,Park, Hyeong Ryool,Naumovich, Yana A.,Zhmurov, Petr A.,Khomutova, Yulia A.,Ioffe, Sema L.,Tartakovsky, Vladimir A.
, p. 8148 - 8159 (2015/02/05)
An approach to the synthesis of α-halo oxime ethers from readily accessible nitronates and nitro compounds via bis-(oxy)enamines is reported. A key step of the strategy involves the unprecedented reaction of bis(oxy)enamines with a metal (Co, Zn, Mg, Mn)
3-Halomethylated cyclic nitronates: Synthesis and nucleophilic substitution
Mikhaylov, Andrey A.,Dilman, Alexander D.,Struchkova, Marina I.,Khomutova, Yulia A.,Korlyukov, Alexander A.,Ioffe, Sema L.,Tartakovsky, Vladimir A.
, p. 4584 - 4594 (2011/07/08)
A method for the introduction of a halogen atom into the methyl group attached to the C-3 atom of five- and six-membered cyclic nitronates (isoxazoline N-oxides and oxazine N-oxides, respectively) has been studied. The process involves silylation of start
