131327-82-7Relevant academic research and scientific papers
RHODIUM CARBENOID MEDIATED CYCLISATIONS. PART 5. SYNTHESIS AND REARRANGEMENT OF CYCLIC SULPHONIUM YLIDES; PREPARATION OF 6- AND 7-MEMBERED SULPHUR HETEROCYCLES
Moody, Christopher J.,Taylor, Roger J.
, p. 6501 - 6524 (2007/10/02)
Treatment of diazo mercaptans with rhodium(II) acetate gives six- and seven-membered sulphur heterocycles; diazo sulphides give cyclic sulphonium ylides, which are isolable, or rearrange, depending on the nature of the substituent on sulphur.
