1313374-67-2Relevant academic research and scientific papers
Conformationally flexible C 3-symmetric 1,3-oxazoles as molecular scaffolds
Shah, Shailesh R.,Thakore, Ruchita R.,Vyas, Trupti A.,Sridhar, Balasubramanian
, p. 294 - 300 (2016)
Flexible-arm, C 3-symmetric tris-oxazoles are synthesized for their applications in supramolecular chemistry and materials science. The C 3-symmetry is introduced starting from 1,3,5-trimethylbenzene and carrying out threefold reactions at each stage of the synthesis. The applicability of these tris-oxazoles is demonstrated by transforming a representative example into a highly fluorescent material. This is accomplished by conjugation with an aromatic moiety via palladium(0)-catalyzed direct arylation at C-2 of the oxazole. A unique molecular arrangement in the crystal structure is observed.
Off-on-off fluorescence pH switch of three trinuclear RuII complexes containing imidazole rings
Cheng, Feixiang,Chen, Jishu,Wang, Fan,Tang, Ning,Chen, Longhai
, p. 766 - 772 (2011)
Three tripodal ligands H3L1-3 containing imidazole rings were synthesized by the reaction of 1,10-phenanthroline-5,6-dione with 1,3,5-tris[(3-formylphenoxy)methyl]benzene, 1,3,5-tris[(3-formylphenoxy)methyl]- 2,4,6-trimethylbenzene,
