1313395-18-4Relevant articles and documents
An Oxidant- And Catalyst-Free Synthesis of Dibenzo[ a, c ]carbazoles via UV Light Irradiation of 2,3-Diphenyl-1 H -indoles
Kang, Yang,Hou, Rong,Min, Xiaoyan,Wang, Tao,Liang, Yong,Zhang, Zunting
, p. 1621 - 1632 (2021/12/13)
An efficient methodology for the synthesis of dibenzo[a,c]- carbazoles via annulation of 2,3-diphenyl-1H-indoles in EtOH under UV light irradiation (λO = 365 nm) along with hydrogen evolution is described. This method exhibits the advantages of mild reaction conditions, no requirement of any oxidants and catalysts, and release of hydrogen as the only byproduct. Notably, the mechanism investigation confirms that the trans-4b,8a-dihydro-9H-dibenzo[a,c]carbazole intermediate could convert into cis-4b,8a-dihydro-9H-dibenzo[a,c]carbazole, which relies on the nitrogen atom of the indole ring. This is followed by intramolecular dehydrogenation which yields the dibenzo[a,c]carbazoles. 2021. Thieme. All rights reserved.
Naphtho-five-membered ring-benzofused heterocyclic organic compounds and application thereof
-
, (2020/07/02)
The invention belongs to the technical field of organic photoelectric materials, and particularly relates to naphtha-five-membered ring-benzofused heterocycle organic compounds and application thereof. The organic compounds disclosed by the invention have a parent structure of naphtho-five-membered ring-benzofused heterocycle, are high in interatomic bond energy, present good thermal stability, are beneficial for intermolecular solid accumulation, and can be used as luminescent layer materials to effectively prolong the service life of materials. The compounds provided by the invention are derivatives of large conjugated fused heterocycles, are applied to light emitting layers, have proper energy levels matched with adjacent layers, facilitate injection of holes and electrons, can effectively reduce turn-on voltage, and can realize good light emitting efficiency in a device due to a relatively high exciton migration rate. The compounds disclosed by the invention have relatively large conjugate planes, are beneficial for molecular accumulation, show good thermodynamic stability and present long service life in devices. A preparation process of the derivatives is simple and feasible,raw materials are easy to obtain, and the derivatives are suitable for large-scale production.
COMPOUND FOR ORGANIC ELECTRIC ELEMENT, ORGANIC ELECTRIC ELEMENT USING SAME, AND ELECTRONIC DEVICE COMPRISING SAME ORGANIC ELECTRONIC ELEMENT
-
Paragraph 0175; 0177; 0181-0182, (2019/05/18)
Provided are an organic electric element and an electronic device comprising the same. According to the present invention, the organic electric element uses a mixture of compounds as a phosphorescent host material which can achieve a high light-emitting efficiency and a low driving voltage and can greatly improve a lifespan in an organic electric element.