1313597-11-3

Basic information

• Product Name: [Au₂(phenylacetylide)(triphenylphosphine)3]OTf
• CAS NO: 1313597-11-3
• Molecular Weight: 1431
• Mol File: 1313597-11-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Au₂(phenylacetylide)(triphenylphosphine)3]OTf(CAS DataBase Reference)
• NIST Chemistry Reference: [Au₂(phenylacetylide)(triphenylphosphine)3]OTf(1313597-11-3)
• EPA Substance Registry System: [Au₂(phenylacetylide)(triphenylphosphine)3]OTf(1313597-11-3)

Safety Data

• Hazardous Substances Data: 1313597-11-3(Hazardous Substances Data)

Upstream product

• 536-74-3 phenylacetylene 
• 61359-40-8 bis(triphenylphosphine)gold(I) triflate 

Relevant articles and documents

Luminescent homo- and heteropolynuclear gold complexes stabilized by a unique acetylide fragment

In this paper we describe the reactivity of the gold acetylide derivatives [Au(C≡CR)(PPh3)] (R = Ph, 2-py). Reactions of these complexes with fragments of the type [M(PPh3)2]+ (M = Au, Ag, Cu) afford a series of novel discrete molecules stabilized not only by interactions with the triple bond but also by the formation of strong metal-gold interactions. The crystal structures of the gold-gold and gold-silver species confirm their similar behavior, while X-ray diffraction establishes a different arrangement for the copper complex with pyridine acetylide as a consequence of the coordination of this metal center to the nitrogen atom of pyridine and to the carbons of the alkyne. The luminescent properties of the complexes were also studied.