1313601-46-5Relevant academic research and scientific papers
Complexes of sterically-hindered diaminophosphinothiolate ligands with Rh(I), Ni(II) and Pd(II)
Robbie, Alasdair J.,Cowley, Andrew R.,Jones, Michael W.,Dilworth, Jonathan R.
, p. 1849 - 1856 (2011/08/04)
Two new sterically demanding diaminophosphinothiolate ligands (HL 1 and HL2) have been prepared and the X-ray crystal structure of the Li salt of HL2 has been determined. The complex [Pd(L1)2] was fully characterized, but in contrast to other phosphinothiolates, complexes with the M(L)3 stoichiometry could not be prepared. Reaction of LH1 with Ni(II) led to cleavage of the arythiolate group and isolation of a thiolate bridged dimer, confirmed by an X-ray crystal structure. The Rh(I) complexes [Rh(nbd)L] (L = L1, L2) were characterized including an X-ray structure.
