1313609-70-9Relevant academic research and scientific papers
Cobalt-catalyzed benzylzincation of alkynes
Murakami, Kei,Yorimitsu, Hideki,Oshima, Koichiro
experimental part, p. 7688 - 7691 (2010/09/10)
Chemical Equotion Present Carbometalation: Cobalt salts catalyze benzylzincation of alkynes to afford benzylated multisubstituted alkenes with high regio- and stereoselectivity. The scope of the reaction is wide enough to apply unfunctionalized alkynes as well as arylacetylenes. The reaction offers a new route to the regio- and stereoselective synthesis of an estrogen receptor antagonist (see scheme).
