1313615-64-3Relevant academic research and scientific papers
HClO4-supported on silica gel: A mild and efficient catalyst for Hosomi-Sakurai reaction
Murugan, Kaliyappan,Chen, Chinpiao
experimental part, p. 5827 - 5830 (2011/12/03)
Perchloric acid supported on silica gel was found to be an efficient catalyst (2 mol %) for the Hosomi- Sakurai allylation of numerous aldehydes with allyltrimethylsilane in the presence of benzyl alcohol. This method was also effective for the allylation of secondary alcohols under mild experimental conditions.
Silicomolybdic acid supported on silica gel: An efficient catalyst for Hosomi-Sakurai reactions
Murugan, Kaliyappan,Srimurugan, Sankareswaran,Chen, Chinpiao
experimental part, p. 5621 - 5629 (2011/08/09)
Silicomolybdic acid that is supported on silica gel (50 wt %) efficiently catalyzes the high-yielding Hosomi-Sakurai allylation of carbonyl compounds by allyltrimethylsilane in the presence of benzyl alcohol. The reaction rates of inactive substrates and the yields were greatly increased when preformed acetals were used as substrates.
