1313617-94-5Relevant academic research and scientific papers
Solvent-catalyzed umpolung carbon–sulfur bond-forming reactions by nucleophilic addition of thiolate and sulfinate ions to in situ–derived nitrosoalkenes in deep eutectic solvents
Dilauro, Giuseppe,Cicco, Luciana,Perna, Filippo Maria,Vitale, Paola,Capriati, Vito
, p. 617 - 623 (2017/05/24)
The low transition temperature mixture formed by lactic acid and choline chloride proved to be effective for an umpolung carbon–sulfur bond formation at the α-position of α-chloro oximes. Aliphatic, aromatic, and heteroaromatic thiolate and sulfinate ions
Catalytic asymmetric addition of thiols to nitrosoalkenes leading to chiral non-racemic α-sulfenyl ketones
Hatcher, John M.,Kohler, Mark C.,Coltart, Don M.
, p. 3810 - 3813 (2011/09/16)
The first asymmetric organocatalytic sulfenylation of in situ derived nitrosoalkenes leading to chiral nonracemic α-sulfenylated ketones is described. The transformation proceeds in an umpolung fashion, relative to enolate/azaenolate methods, and uses simple thiols, thereby obviating the need for electrophilic sulfur reagents.
