131367-07-2Relevant academic research and scientific papers
OUVERTURE PAR HF-PYRIDINE D'AZIRIDINES TRICYCLIQUES III. COMPARAISON ENTRE LA REACTIVITE DES AZIRIDINES ET CELLE DES OXIRANES
Girault, Y.,Rouillard, M.,Decouzon, M.,Geribaldi, S.
, p. 231 - 246 (1990)
The ring opening of 3-aza 1,8,8-trimethyl tricyclo2.4>octane isomers by HF-pyridine has been studied.A series of γ-fluoroamines and non fluorinated amines, isomers of the starting aziridines, was obtained.No β-fluoroamines were isolated.The structures of diastereoisomeric amines, established by 1H and 19F NMR, show product structure dependence upon the exo-endo aziridine configuration.A comparison between aziridine reactivity and oxirane one is done.
