1313728-42-5

Basic information

• Product Name: 4H-1-Benzopyran-4-one, 6-broMo-7-hydroxy-
• Synonyms: 4H-1-Benzopyran-4-one, 6-broMo-7-hydroxy-
• CAS NO: 1313728-42-5
• Molecular Formula: C₉H₅BrO₃
• Molecular Weight: 241.0382
• Mol File: 1313728-42-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4H-1-Benzopyran-4-one, 6-broMo-7-hydroxy-(CAS DataBase Reference)
• NIST Chemistry Reference: 4H-1-Benzopyran-4-one, 6-broMo-7-hydroxy-(1313728-42-5)
• EPA Substance Registry System: 4H-1-Benzopyran-4-one, 6-broMo-7-hydroxy-(1313728-42-5)

Safety Data

• Hazardous Substances Data: 1313728-42-5(Hazardous Substances Data)

Upstream product

• 60965-25-5 5'-bromo-2',4'-dihydroxyacetophenone 
• 1313728-40-3 6-bromo-2-hydroxy-7-(methoxymethoxy)chroman-4-one 
• 1313728-38-9 1-[5-bromo-2-hydroxy-4-(methoxymethoxy)phenyl]ethenone 
• 1313728-48-1 6-bromo-7-(methoxymethoxy)chromone 
• 140-88-5 ethyl acrylate 
• 3054-95-3 acrylaldehyde diethyl acetal 
• 1313728-46-9 7-acryloyloxy-6-bromochromone 
• 89-84-9 2',4'-dihydroxy-4-acetophenone 
• 100-42-5 styrene 
• 1313728-44-7 7-acetoxy-6-bromochromone 

Downstream Products

• 1313728-53-8 (E)-7-hydroxy-6-styrylchromone 
• 1313728-54-9 2-phenyl-5H-furo[3,2-g]chromen-5-one 
• 1313728-55-0 (E)-7-methoxymethoxy-6-styrylchromone 
• 1313728-56-1 (E)-7-benzyloxy-6-styrylchromone 
• 1313728-59-4 ethyl (E)-3-(7-benzyloxy-4-oxo-4H-1-benzopyran-6-yl)acrylate 
• 1313728-62-9 (E)-3-(7-benzyloxy-4-oxo-4H-1-benzopyran-6-yl)-2-propenal 
• 1313728-63-0 ethyl 3-(7-benzyloxy-4-oxo-4H-1-benzopyran-6-yl)propanoate 
• 1313728-65-2 (Z)-3-(7-benzyloxy-4-oxo-4H-1-benzopyran-6-yl)acrylonitrile 
• 1313728-64-1 (E)-3-(7-benzyloxy-4-oxo-4H-1-benzopyran-6-yl)acrylonitrile 
• 1313728-50-5 7-benzyloxy-6-bromochromone 

Relevant articles and documents

The heck reaction of protected hydroxychromones: On route to natural products

The Heck reaction has been successfully extended to the bromochromones with an adjacent protected phenolic hydroxy group which offers a new methodology to various naturally occurring derivatives including tricyclic O-heterocycles. Phosphine-free coupling conditions are found to be effective. Surprisingly, the methoxymethyl protecting group is unstable in several cases but benzyl proved to be an ideal protecting group which could be selectively cleaved by boron trihalides in good yields. CSIRO 2011.