1313812-97-3Relevant academic research and scientific papers
Regioselective synthesis of 3-substituted pyrroles by nucleophilic addition of 3-(1-arylsulfonylalkyl) pyrroles activated under basic or acid conditions
Martinelli, Fabio,Palmieri, Alessandro,Petrini, Marino
, p. 7183 - 7187 (2011/09/15)
Conditioned pyrroles! Sulfonyl pyrroles, obtained regioselectively from commercial N-triisopropylsilylpyrrole, undergo removal of the arylsulfonyl group under basic or acidic conditions to give vinylogous imino-like derivatives (see scheme; TIPS=triisopropylsilyl). These electrophilic intermediates react with nucleophilic reagents to give 3-functionalized pyrroles. Copyright
