131389-31-6Relevant articles and documents
Cyanuric chloride-dimethylformamide mediated cleavage of cyclopropylcarbinols-synthesis of phenolic antioxidant and construction of a new vinylcyclopropane skeleton
Khan, Sagar,Roy, Sanchita,Roy, Rimi,Ghatak, Avishek,Pramanik, Amit,Bhar, Sanjay
supporting information, p. 5019 - 5024 (2015/01/08)
Differently substituted cyclopropylcarbinols underwent ring cleavage with easily accessible cyanuric chloride-N,N-dimethylformamide adduct to produce homoallylic chlorides or dienes depending on the nature and location of the substituents. A mechanistic explanation of the aforesaid observations has been provided. A promising antioxidant compound was prepared following this protocol and studied against Fenton's reagent. This methodology was utilized to construct hitherto unreported vinylcyclopropane frameworks bearing homoallylic chloride and diene moieties.