131393-73-2Relevant academic research and scientific papers
Nucleophilic vinyl substitution in 1-Arylthio(sulfonyl)-2-nitroalkenes
Pavlova,Lipina,Kasem,Kuz'mina
, p. 1321 - 1325 (2007/10/03)
Reactions of 1-arylthio-2-nitroalkenes and 1-arylsulfonyl-2-nitroalkenes with N-, O-, and S-nucleophiles result in replacement of the sulfur-containing group. 1-Arylthio-2-nitroalkenes react with arenethiolates with replacement of the nitro group, yielding the corresponding 1,2-bis(arylthio)alkenes.
STEREOCHEMISTRY OF THE THIYLATION OF 1,2-DINITROALKENES AND 1,4-DINITRO-1,3-DIENES
Mukhina, E. S.,Berkova, G. A.,Pavlova, Z. F.,Lipina, E. S.,Perekalin, V. V.
, p. 1249 - 1254 (2007/10/02)
In thiylation with arenethiolates 1,2-dinitroalkenes form 1-nitro-2-arylthioalkenes in the more stable Z form, and in the absence of a base they form a mixture of the Z and E isomers.During thiylation with arenethiols 1,4-dinitro-1,3-butadienes only give (E,E)-1-nitro-4-arylthio-1,3-dienes.
