131408-03-2Relevant academic research and scientific papers
Copper(I) and silver(I) complexes of the crown thioether ligand 2,5,8-trithia[9]-o-benzenophane (TT[9]OB). Structures of [Cu(PPh2Me)(TT[9]OB)][ClO4] and [Ag(PPh3)(TT[9]OB)][ClO4]
De Groot, Broer,Giesbrecht, Garth R.,Loeb, Stephen J.,Shimizu, George K. H.
, p. 177 - 182 (2008/10/08)
The crown thioether ligand 2,5,8-trithia[9]-o-benzenophane, TT[9]OB, was prepared in 90-95% yield via the Cs+-mediated cyclization of α,α′-dibromo-o-xylene and 3-thiapentane-1,5-dithiol. This thioether ligand reacted with [Cu(CH3CN)
