1314098-17-3Relevant articles and documents
Control over the oxidative reactivity of metalloporphyrins. Efficient electrosynthesis of meso,meso-linked zinc porphyrin dimer
Dime, Abdou K. D.,Devillers, Charles H.,Cattey, Helene,Habermeyer, Benoit,Lucas, Dominique
experimental part, p. 929 - 936 (2012/03/22)
The electrochemical oxidation of zinc(ii) 5,15-p-ditolyl-10-phenylporphyrin at its first oxidation potential leads to the formation of the corresponding meso-meso porphyrin dimer as the main product. The number of electrons abstracted, the addition of the hindered base 2,6-lutidine as well as operating in DMF, instead of a CH2Cl2/CH3CN mixture are the key parameters to obtain high yields of the desired coupling product. Indeed, when the electrolyses are carried out in the CH2Cl 2/CH3CN mixture, the unexpected zinc(ii) 5-chloro-10,20-p-ditolyl-15-phenyl porphyrin is produced as a by-product, the chlorine atom originating from the CH2Cl2 solvent. The monomer and the dimer are characterised by electrochemical analysis. The signature of the dimer is clearly distinguished on the cyclic voltammogram of the monomer on condition of the prior addition of 2,6-lutidine as a hindered base, indicating that the dimerisation process is thus strongly accelerated. Besides, unprecedented X-ray crystallographic structures of the monomer and the meso-meso dimer are presented and their respective structural parameters are compared.
Facile formation of a meso-meso linked porphyrin dimer catalyzed by a manganese(iv)-oxo porphyrin
Takai, Atsuro,Habermeyer, Benoit,Fukuzumi, Shunichi
supporting information; experimental part, p. 6804 - 6806 (2011/08/22)
A manganese(iv)-oxo porphyrin catalyzes C-C bond formation between zinc porphyrins at the meso-position with a two-electron oxidant to afford the meso-meso linked porphyrin dimer efficiently. The meso-meso linked dimer is formed via formation of the porph
