1314102-50-5

Basic information

• Product Name: (2R,3R,4S,5R,6R)-2-(acetoxymethyl)-6-(3-((1S,2S)-2-(diphenylphosphino)cyclohexyl)thioureido)-tetrahydro-2H-pyran-3,4,5-triyl triacetate
• Synonyms: (2R,3R,4S,5R,6R)-2-(acetoxymethyl)-6-(3-((1S,2S)-2-(diphenylphosphino)cyclohexyl)thioureido)-tetrahydro-2H-pyran-3,4,5-triyl triacetate
• CAS NO: 1314102-50-5
• Molecular Weight: 672.736
• Mol File: 1314102-50-5.mol

Chemical Properties

• CAS DataBase Reference: (2R,3R,4S,5R,6R)-2-(acetoxymethyl)-6-(3-((1S,2S)-2-(diphenylphosphino)cyclohexyl)thioureido)-tetrahydro-2H-pyran-3,4,5-triyl triacetate(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R,4S,5R,6R)-2-(acetoxymethyl)-6-(3-((1S,2S)-2-(diphenylphosphino)cyclohexyl)thioureido)-tetrahydro-2H-pyran-3,4,5-triyl triacetate(1314102-50-5)
• EPA Substance Registry System: (2R,3R,4S,5R,6R)-2-(acetoxymethyl)-6-(3-((1S,2S)-2-(diphenylphosphino)cyclohexyl)thioureido)-tetrahydro-2H-pyran-3,4,5-triyl triacetate(1314102-50-5)

Safety Data

• Hazardous Substances Data: 1314102-50-5(Hazardous Substances Data)

Upstream product

• 926924-52-9 (2S,3S,4R,5S,6S)-2-(acetoxymethyl)-6-azidotetrahydro-2H-pyran-3,4,5-triyltriacetate 
• 926924-53-0 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosylamine 
• 1440198-75-3 glycosyl isothiocyanate 
• 452304-63-1 (1S,2S)-2-(diphenylphosphaneyl)cyclohexan-1-amine 
• 14152-97-7 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl isothiocyanate 

Relevant articles and documents

Bifunctional (Thio)urea-Phosphine Organocatalysts Derived from d -Glucose and α-Amino Acids and Their Application to the Enantioselective Morita-Baylis-Hillman Reaction

Novel (thio)urea-tertiary phosphines were developed for use as bifunctional organocatalysts readily available from naturally occurring molecules: saccharides and amino acids. The efficiency of the organocatalysts was demonstrated in the asymmetric Morita-

Enantioselective Morita-Baylis-Hillman reaction organocatalyzed by glucose-based phosphinothiourea

A class of bifunctional phosphinothioureas derived from saccharide was developed as new organocatalysts for the enantioselective Morita-Baylis-Hillman reaction between acrylates and aldehydes. With 10 mol% of glucose-based phosphinothiourea 1d, the allylic alcohols were obtained in up to 96% yield and 83% ee under mild reaction conditions.