1314185-22-2Relevant academic research and scientific papers
One pot iridium-catalyzed asymmetrical double allylations of sodium sulfide: A fast and economic way to construct chiral C2-symmetric bis(1-substituted-allyl)sulfane
Zheng, Shengcai,Huang, Weiqing,Gao, Ning,Cui, Ruimin,Zhang, Min,Zhao, Xiaoming
supporting information; experimental part, p. 6969 - 6971 (2011/08/06)
One pot asymmetrical double allylations of sodium sulfide catalyzed by an iridium complex along with a combination of caesium fluoride and water in dichloromethane have been realized and the double allylation products with two C-S bond chiral centers were obtained in 67-99% yields with b/l 81/19-99/1, dr 85/15-99/1, and 96-99% ee.
