1314243-11-2

Basic information

• Product Name: (E)-(3-azido-3-phenylallyloxy)(tert-butyl)diphenylsilane
• Synonyms: (E)-(3-azido-3-phenylallyloxy)(tert-butyl)diphenylsilane
• CAS NO: 1314243-11-2
• Molecular Weight: 413.594
• Mol File: 1314243-11-2.mol

Chemical Properties

• CAS DataBase Reference: (E)-(3-azido-3-phenylallyloxy)(tert-butyl)diphenylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(3-azido-3-phenylallyloxy)(tert-butyl)diphenylsilane(1314243-11-2)
• EPA Substance Registry System: (E)-(3-azido-3-phenylallyloxy)(tert-butyl)diphenylsilane(1314243-11-2)

Safety Data

• Hazardous Substances Data: 1314243-11-2(Hazardous Substances Data)

Upstream product

• 258281-81-1 tert-butyl(cinnamyloxy)diphenylsilane 
• 1314243-43-0 (E)-3-azido-3-phenylprop-2-en-1-ol 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 1314243-38-3 2-(2-(3,4-diphenylisoquinolin-1-yl)-2-hydroxyethyl)isoindoline-1,3-dione 
• 1314243-43-0 (E)-3-azido-3-phenylprop-2-en-1-ol 
• 1314243-13-4 (E)-2-(3-azido-3-phenylallyl)isoindoline-1,3-dione 
• 1314243-12-3 (E)-(3-(allyloxy)-1-azidoprop-1-enyl)benzene 

Relevant articles and documents

[3 + 2]-Cycloadditions of nitrile ylides after photoactivion of vinyl azides under flow conditions

The photodenitrogenation of vinyl azides to 2H-azirines by using a photoflow reactor is reported and compared with thermal formation of 2H-azirines. Photochemically, the ring of the 2H-azirines was opened to yield the nitrile ylides, which underwent a [3 + 2]-cycloaddition with 1,3-dipolarophiles. When diisopropyl azodicarboxylate serves as the dipolarophile, 1,3,4-triazoles become directly accessible starting from the corresponding vinyl azide.

Synthesis of isoquinolines from α-aryl vinyl azides and internal alkynes by Rh-Cu bimetallic cooperation

Catalysts in a relay: A synthetic method for delivering highly substituted isoquinolines has been developed (see scheme; Cp =C5Me5, DMF=N,N-dimethylformamide, TEMPO=2,2,6,6-tetramethylpiperidine-1-oxyl). A preliminary mechanistic study showed that the rhodium and copper cooperate synergistically in the multistep sequence.