1314243-37-2Relevant academic research and scientific papers
Synthesis of isoquinolines from α-aryl vinyl azides and internal alkynes by Rh-Cu bimetallic cooperation
Wang, Yi-Feng,Toh, Kah Kah,Lee, Jian-Yuan,Chiba, Shunsuke
supporting information; experimental part, p. 5927 - 5931 (2011/08/02)
Catalysts in a relay: A synthetic method for delivering highly substituted isoquinolines has been developed (see scheme; Cp =C5Me5, DMF=N,N-dimethylformamide, TEMPO=2,2,6,6-tetramethylpiperidine-1-oxyl). A preliminary mechanistic study showed that the rhodium and copper cooperate synergistically in the multistep sequence.
