131451-71-3

Basic information

• Product Name: {(1R,2R,4aS,5S,8aS)-2-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-methoxymethoxy-1,2,4a,5,6,7,8,8a-octahydro-naphthalen-1-yl}-methanol
• CAS NO: 131451-71-3
• Molecular Weight: 508.773
• Mol File: 131451-71-3.mol

Chemical Properties

• CAS DataBase Reference: {(1R,2R,4aS,5S,8aS)-2-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-methoxymethoxy-1,2,4a,5,6,7,8,8a-octahydro-naphthalen-1-yl}-methanol(CAS DataBase Reference)
• NIST Chemistry Reference: {(1R,2R,4aS,5S,8aS)-2-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-methoxymethoxy-1,2,4a,5,6,7,8,8a-octahydro-naphthalen-1-yl}-methanol(131451-71-3)
• EPA Substance Registry System: {(1R,2R,4aS,5S,8aS)-2-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-methoxymethoxy-1,2,4a,5,6,7,8,8a-octahydro-naphthalen-1-yl}-methanol(131451-71-3)

Safety Data

• Hazardous Substances Data: 131451-71-3(Hazardous Substances Data)

Upstream product

• 131451-61-1 C₂₇H₅₀O₅Si₂ 
• 131451-66-6 Acetic acid (1R,4S,4aR,8R,8aR)-8-acetoxy-4-(tert-butyl-dimethyl-silanyloxymethyl)-1,4,4a,5,6,7,8,8a-octahydro-naphthalen-1-yl ester 
• 131451-69-9 2-[(1R,2R,4aS,5S,8aS)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-5-methoxymethoxy-1,2,4a,5,6,7,8,8a-octahydro-naphthalen-2-yl]-ethanol 
• 131451-70-2 (1S,4aS,5R,6R,8aS)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-1-methoxymethoxy-1,2,3,4,4a,5,6,8a-octahydro-naphthalene 

Downstream Products

• 131451-72-4 (1R,2R,4aS,5S,8aR)-2-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-methoxymethoxy-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid 

Relevant articles and documents

Synthesis of the bottom half of chlorothricolide

Diels-Alder reaction of 1-acetoxy-pentadienol derivative 5 with cyclohexenone afforded cycloadduct 6 which gave with base the transoctahydronaphthalene skeleton 4. Diastereoselective reduction of the keto group and then Claisen-Ireland rearrangement furni