131480-06-3Relevant academic research and scientific papers
Micellar solution of sodium dodecyl sulfate (SDS) catalyzes Kabacknik-Fields reaction in aqueous media
Sobhani, Sara,Vafaee, Asieh
experimental part, p. 1909 - 1915 (2009/12/30)
A new, convenient and high-yielding procedure for the one-pot synthesis of diethyl α-aminophosphonates from aldehydes, amines and diethyl phosphite (Kabacknik-Fields reaction) in SDS micellar solution in aqueous media is described. The synthesis of aaminophosphonates in the present study represents a three-component reaction in which no intermediate formation of either an imine or α-hydroxyphosphonate was observed. Georg Thieme Verlag Stuttgart.
Synthesis of organophosphorus compounds via silyl esters of phosphorous acids
Afarinkia, Kamyar,Rees, Charles W.,Cadogan, John I. G.
, p. 7175 - 7196 (2007/10/02)
The addition of trimethylsilyloxy phosphorus (III)derivatives generated in situ to imines at room temperature provides a mild selective and high yielding route to α-aminoalkylphosphorate and α-aminoalkylphenylphosphinate esters. Isocyanates and carbodiimides react similarly to give phosphonoureas and phosphonoguarnidines respectively aldehydes and ketones are much less reactive and cyanides are inert.
