1314805-30-5

Basic information

• Product Name: Br^(1-)*C₂₄H₂₇NOP⁽¹⁺⁾
• Synonyms: Br^(1-)*C₂₄H₂₇NOP⁽¹⁺⁾
• CAS NO: 1314805-30-5
• Molecular Weight: 456.362
• Mol File: 1314805-30-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Br^(1-)*C₂₄H₂₇NOP⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: Br^(1-)*C₂₄H₂₇NOP⁽¹⁺⁾(1314805-30-5)
• EPA Substance Registry System: Br^(1-)*C₂₄H₂₇NOP⁽¹⁺⁾(1314805-30-5)

Safety Data

• Hazardous Substances Data: 1314805-30-5(Hazardous Substances Data)

Upstream product

• 1314805-22-5 Br^(1-)*C₂₆H₂₉NO₃P⁽¹⁺⁾ 

Relevant articles and documents

Thermogravimetrical investigations of the dealkoxycarbonylation of N-acyl-α-triphenylphosphonioglycinates

Thermogravimetrical experiments revealed that immediately after the endothermic process of the melting of N-acyl-α- triphenylphosphonioglycinates 1, an exothermic demethoxycarbonylation of phosphonioglycinates commenced, accompanied by the release of CO2. The residues contained the corresponding N-acylaminomethyltriphenylphosphonium salts 2 (18.3-49.5%), methyltriphenylphosphonium salts 7 (21.8-67.9%), and the corresponding 1,2-di(N-acylamino)fumaric acid dimethyl ester 6 (2.1-26.0%). When the reaction was carried out in the presence of Ph3P and the corresponding triphenylphosphine hydrobromide, hydroiodide, or tetrafluoroborate, N-acyl-α-triphenylphosphoniumglycinate bromides and iodides 1a-f underwent demethoxycarbonylation to form the corresponding N-acylaminomethyltriphenylphosphonium salts 2a-f at 95-130 °C in good to excellent yields (79-100%). On the other hand, tetrafluoroborates 1g-i underwent corresponding reactions at about 170-175 °C to give phosphonium tetrafluoroborates 2g-i in much lower yields (34-67%). Plausible mechanisms of the investigated reaction are discussed. It was also demonstrated that the obtained crude α-(N-acylamino)alkyltriphenylphosphonium salts 2 could be applied as valuable α-amidoalkylating agents in spite of their contamination with inert methyltriphenylphosphonium salts 7.