1314865-12-7Relevant academic research and scientific papers
Synthesis of the tetrasaccharide related to the repeating unit of the O-antigen from Azospirillum brasilense Jm125A2 in the form of its 2-aminoethyl glycoside
Sarkar, Vikramjit,Mukhopadhyay, Balaram
, p. 13 - 18 (2018)
Total chemical synthesis of the linear tetrasaccharide repeating unit β-D-Glc-(1 → 2)-α-L-Rha-(1 → 3)-α-L-Rha-(1 → 2)-α-L-Rha-CH2CH2NH2 of the O-antigen from Azospirillum brasilense Jm125A2 is accomplished through rational
Access to antigens related to anthrose using pivotal cyclic sulfite/sulfate intermediates
Milhomme, Ophelie,John, Cedric,Djedaini-Pilard, Florence,Grandjean, Cyrille
experimental part, p. 5985 - 5998 (2011/09/16)
Anthrose is the upstream terminal unit of the tetrasaccharide side chain from a major glycoprotein of Bacillus anthracis exosporium and is part of important antigenic determinants. A novel entry to anthrose-containing antigens and precursors is described. The synthetic route, starting from d(+)-fucose, makes use of intermediates featuring a cyclic sulfite or sulfate function which serves successively as a protecting and a leaving group.
