1314894-77-3Relevant academic research and scientific papers
Catalytic α-monoallylation of aryl acetonitriles
Maji, Tapan,Tunge, Jon A.
supporting information, p. 5072 - 5075 (2014/12/11)
α-Cyano aldehydes undergo selective transition-metal-catalyzed monoallylation to provide α-allylated nitriles. The transformation leads to linear substitution products with palladium catalysts or branched allylated nitriles using an iridium catalyst. Faci
A new synthesis of pyrrolidines by way of an enantioselective Mannich/diastereoselective hydroamination reaction sequence
Baxter Vu, Jenny M.,Leighton, James L.
supporting information; experimental part, p. 4056 - 4059 (2011/09/21)
A new two-step synthesis of highly substituted pyrrolidines has been developed. Chiral silane Lewis acid promoted enantioselective Mannich reactions of silyl ketene imines with acylhydrazones may be used to access bishomoallylic benzoic hydrazides that in
