13149-79-6Relevant articles and documents
Preparation method of cyclododecanone oxime
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Paragraph 0037-0039; 0084-0086, (2019/07/31)
The invention discloses a preparation method of cyclododecanone oxime. The method comprises the steps of mixing cyclododecanone, a small-molecular oxime, an organic silicone ether, a pH buffer agent and a solvent, adjusting the pH of the system to 1-3 by using an acidic catalyst and performing an oxime exchange reaction. According to the method provided by the invention, the reaction is a homogeneous system, the mass transfer requirements are low, and reaction products have no ammonium sulfate by-products; after the reaction is completed, a reaction liquid is subjected to rectification to separate small-molecular ketones, so that the problem of difficult oil-water separation of hydroxylamine oximation can be solved; and the method has a high raw material conversion rate and high product selectivity.
A 13C NMR Study of Formaldehyde Association in an Ethylene Glycol Solution
Balashov, A. L.,Danov, S. M.,Krasnov, V. L.,Chernov, A. Yu.,Ponomarev, A. N.,Borisova, I. A.
, p. 900 - 903 (2007/10/03)
The qualitative and quantitative composition of solutions of formaldehyde in ethylene glycol is studied by the 13C NMR method at 90 deg C in the range of formaldehyde concentrations from 0 to 20 mol/l.Equilibrium constants of polycondensation are determined for hemiformals H(OCH2)nOCH2CH2OH and H(OCH2)mOCH2CH2O(CH2O)kH (n, m, k = 1, 2, >/= 3).