1314918-30-3Relevant academic research and scientific papers
Identification of 3,6-di-O-acetyl-1,2,4-O-orthoacetyl-α-d- glucopyranose as a direct evidence for the 4-O-acyl group participation in glycosylation
Ma, Yuyong,Lian, Gaoyan,Li, Yao,Yu, Biao
, p. 7515 - 7517 (2011/09/13)
The formation of 3,6-di-O-acetyl-1,2,4-O-orthoacetyl-α-d- glucopyranose was observed in the gold(i)-catalyzed glycosidation of peracetyl glucopyranosyl ortho-hexynylbenzoate; experiments with substrates bearing deuterium labeled 2-O-acetyl or 4-O-acetyl groups indicated that the orthoacetate was derived from the 4-O-acetyl group, which provided a direct evidence for the remote participation of the 4-O-acyl group in glycosylation.
